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Ohio Utica Shale

Researchers say industrial wastes can be turned into proppants

By Bob Downing Published: February 17, 2014

From Penn State University:

 

UNIVERSITY PARK, Pa. -- Industrial and domestic waste materials are viable alternative sources of raw materials for engineering proppants -- particles used to open rock fractures -- for use in shale gas and oil recovery, according to Penn State material scientists John Hellmann and Barry Scheetz.

Writing in the current issue of American Ceramic Society Bulletin, the researchers describe innovative approaches for engineering high-performance ceramic proppants from waste streams including mixed glass cullet, mine tailings and even drill-cuttings from shale gas wells themselves.

In Pennsylvania, horizontal drilling and hydraulic simulation, more commonly referred to as hydrofracturing, are techniques used to extract gas from reserves where it is trapped in less permeable, tight shale formations such as the Marcellus and Utica plays.

In the hydrofracturing process, a mixture of water, silica sand or other particles, and chemicals is injected at high pressure into the well, causing the rock to fracture and release the gas. The sand and other particles are referred to as proppants since they are used to “prop” open the rock fractures, thereby creating a pathway for the gas to flow from the shale and into the well.

“Silica sand is relatively inexpensive, available and has a long track record of use as a proppant," said Hellmann. "However, sand particles are quite angular and tend to pack. It also typically exhibits lower crush strengths and results in lower permeabilities relative to synthetic proppants, like the ones we are researching. Spherical particles, characteristic of the synthetic proppants, flow better, require less water and chemical additives for placement, and maintain higher permeability for longer periods of time than angular sand particles.”

Silica sands are routinely employed in the relatively shallow deposits, such as the Marcellus shale. Hellman said engineered synthetic proppants, which are substantially stronger and more spherical, will be required for deeper deposits that contain other condensed phases and that experience substantially higher closer stresses, such as the Utica and Bakken plays.”

According to Industrial Minerals, a market leading resource for minerals intelligence, each year more than 30 million tons of proppants are used in hydrofracturing, and demand is projected to increase to 45 million tons by 2017. Engineering proppants from waste materials offers not only a savings in costs but the additional environmental benefit of diverting millions of tons of waste from landfills.

“Our engineered materials have the potential to not only provide a new source of high-performance proppants, but at the same time do so in a potentially more environmentally conscious way," said Hellmann. "Waste materials are diverted from landfills and are used to engineer proppants that are more efficient, requiring less water and less chemical additives in the hydrofracturing process – that’s a pretty green message.”

Hellmann is professor of materials science and engineering and associate dean for education in the College of Earth and Mineral Sciences. Scheetz is a professor of materials, civil and nuclear engineering in the College of Engineering. Other authors include Hellmann and Scheetz's former students Walter Luscher, Pacific Northwest National Laboratory; David Hartwich, ceramic research engineer at ANH Refractories; and Ryan Koseski, senior research engineer at Saint-Gobain North American R&D Center.

The January/February 2014 edition of the American Ceramic Society Bulletin is available online at http://ceramics.org/publications-and-resources/the-bulletin-of-the-american-ceramic-society.

Professors Hellmann and Scheetz are founding directors and officers of Nittany Extraction Technologies LLC, which licenses intellectual property related to core-shell microstructural evolution in proppants and manufacturing of glass-ceramic proppants from Penn State. These relationships have been reviewed by the University’s Institutional Conflict of Interest Committee and are currently being managed by the University.

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Ohio Department of Natural Resources' Division of Oil and Gas Resources Management State agency Web site.

ODNR Division of Oil and Gas Resources Management. State drilling permits. List is updated weekly.

ODNR Division of Geological Survey.

Ohio Environmental Protection Agency.

Ohio State University Extension.

Ohio Farm Bureau.

Ohio Oil and Gas Association, a Granville-based group that represents 1,500 Ohio energy-related companies.

Ohio Oil & Gas Energy Education Program.

Energy In Depth, a trade group.

Marcellus and Utica Shale Resource Center by Ohio law firm Bricker & Eckler.

Utica Shale, a compilation of Utica shale activities.

Landman Report Card, a site that looks at companies involved in gas and oil leases.FracFocus, a compilation of chemicals used in fracking individual wells as reported voluntarily by some drillers.

Chesapeake Energy Corp,the Oklahoma-based firm is the No. 1 driller in Ohio.

Rig Count Interactive Map by Baker Hughes, an energy services company.

Shale Sheet Fracking, a Youngstown Vindicator blog.

National Geographic's The Great Shale Rush.

The Ohio Environmental Council, a statewide eco-group based in Columbus.

Buckeye Forest Council.

Earthjustice, a national eco-group.

Stop Fracking Ohio.

People's Oil and Gas Collaborative-Ohio, a grass-roots group in Northeast Ohio.

Concerned Citizens of Medina County, a grass-roots group.

No Frack Ohio, a Columbus-based grass-roots group.

Fracking: Gas Drilling's Environmental Threat by ProPublica, an online journalism site.

Penn State Marcellus Center.

Pipeline, blog from Pittsburgh Post-Gazette on Marcellus shale drilling.

Allegheny Front, environmental public radio for Western Pennsylvania.